高等有机化学:反应与合成.pdf

高等有机化学:反应与合成.pdf
 

书籍描述

编辑推荐
《高等有机化学:反应与合成(第5版)》可供有机化学、药物化学和生物化学等专业的高年级本科生、研究生以及相关领域的科研人员参考。

作者简介
作者:(美国)卡雷 (Carey.F.A.) (美国)松德贝里 (Sundberg.R.J.)

目录
Preface
AcknowledgmentandPersonalStatement
Introduction

Chapter1.AlkylationofEnolatesandOtherCarbonNucleophiles
Introduction
1.1.GenerationandPropertiesofEnolatesandOtherStabilizedCarbanions
1.1.1.GenerationofEnolatesbyDeprotonation
1.1.2.RegioselectivityandStereoselectivityinEnolateFormationfromKetonesandEsters
1.1.3.OtherMeansofGeneratingEnolates
1.1.4.SolventEffectsonEnolateStructureandReactivity
1.2.AlkylationofEnolates
1.2.1.AlkylationofHighlyStabilizedEnolates
1.2.2.AlkylationofKetoneEnolates
1.2.3.AlkylationofAldehydes,Esters,CarboxylicAcids,Amides,andNitriles
1.2.4.GenerationandAlkylationofDianions
1.2.5.IntramolecularAlkylationofEnolates
1.2.6.ControlofEnantioselectivityinAlkylationReac:ions
1.3.TheNitrogenAnalogsofEnolsandEnolates:EnaminesandImineAnions

GeneralReferences
Problems
Chapter2.ReactionsofCarbonNucleophileswithCarbonylCompounds
Introduction
2.1.AldolAdditionandCondensationReactions
2.1.1.TheGeneralMechanism
2.1.2.ControlofRegio-andStereoselectivityofAldolReactionsofAldehydesandKetones
2.1.3.AldolAdditionReactionsofEnolatesofEstersandOtherCarbonylDerivatives
2.1.4.TheMukaiyamaAldolReaction
2.1.5.ControlofFacialSelectivityinAldolandMukaiyamaAldolReactions
2.1.6.IntramolecularAldolReactionsandtheRobinsonAnnulation

2.2.AdditionReactionsofIminesandIminiumIons
2.2.1.TheMannichReaction
2.2.2.AdditionstoN-AcylIminiumIons
2.2.3.Amine-CatalyzedCondensationReactions

2.3.AcylationofCarbonNucleophiles
2.3.1.ClaisenandDieckmannCondensationReactions
2.3.2.AcylationofEnolatesandOtherCarbonNucleophiles

2.4.OlefinationReactionsofStabilizedCarbonNucleophiles
2.4.1.TheWittigandRelatedReactionsofPhosphorus-StabilizedCarbonNucleophiles
2.4.2.Reactionsofa-TrimethyisilylcarbanionswithCarbonylCompounds
2.4.3.TheJuliaOlefinationReaction

2.5.ReactionsProceedingbyAddition-Cyclization
2.5.1.SulfurYiidesandRelatedNucleophiles
2.5.2.NucleophilicAddition-Cyclizationofot-Haloesters

2.6.ConjugateAdditionbyCarbonNucleophiles
2.6.1.ConjugateAdditionofEnolates
2.6.2.ConjugateAdditionwithTandemAlkylation
2.6.3.ConjugateAdditionbyEnolateEquivalents
2.6.4.ControlofFacialSelectivityinConjugateAdditionReactions
2.6.5.ConjugateAdditionofOrganometallicReagents
2.6.6.ConjugateAdditionofCyanideIon

GeneralReferences
Problems
Chapter3.FunctionalGroupInterconversionbySubstitution,IncludingProtectionandDeprotection
Introduction
3.1.ConversionofAlcoholstoAlkylatingAgents
3.1.1.SulfonateEsters
3.1.2.Halides

Chapter4.ElectrophilicAdditionstoCarbon-CarbonMultipleBonds
Chapter5.ReductionofCarbon-CarbonMultipleBonds,CarbonylCroups,andOtherFunctionalGroups
Chapter6.ConcertedCycloadditions,UnimolecularRearrangements,andThermalEliminations
Chapter7.OrganometallicCompoundsofGroupIandIIMetals
Chapter8.ReactionsInvolvingTransitionMetals
Chapter9.Carbon-CarbonBond-FormingReactionsofCompoundsofBoron,Silcon,andTin
Chapter10.ReactionsInvolvingCarbocations,Carbenes,andRadicalsandReactiveIntermediates
Chapter11.AromaticSubstitutionReactions
Chapter12.Oxidations
Chapter13.MultistepSyntheses
References
Index

文摘
插图:

高等有机化学:反应与合成

内容简介
《高等有机化学:反应与合成(第5版)》是《高等有机化学:反应与合成(第5版)》的新版,自从1977年面世以来,《高等有机化学:反应与合成(第5版)》作为学科首选教材的地位一直没有动摇过,广泛地覆盖了有机化合物的结构、反应活性及合成。她的第五版相对2001年出版的第四版进行了大幅度的修订,更新了学科发展的相关资料,内容组织更加清晰明朗,特别是计算化学部分。通过控制反应而得到特定的合成是有机合成的全部目标。PartB在不同反应类型的基础上详尽地描述了最常见的和最有用的合成反应。每章后附有习题精选及解答习题的推荐参考文献。

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